Innovating Organocatalysis as Promising Trend in Oxidation Reactions with Molecular Oxygen
DOI:
https://doi.org/10.15407/scine11.06.055Keywords:
5 hydroxymethylfurfural, aerobic oxidation, coal, dimethyl sulfoxide, hydrocarbons, N hydroxyphthalimide, organocatalysisAbstract
The prospects for innovative organocatalytic aerobic oxidation developed by IPOCC of the NAS of Ukraine have been outlined. The practice of oxidizing the hydrocarbons and 5-hydroxymethylfurfural with molecular oxygen under mild conditions has been improved by using the organic compound, N-hydroxyphthalimide, as key catalyst. For the oxidation of coal and substrates whole molecules are capable of keto-enol tautomerism, the use of dimethyl sulfoxide as a solvent is an innovative method that ensures the action of basic catalysts.
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