Classical, barrierless, and activationless discharge of palladium(II) iminodiacetate complexes
DOI:
https://doi.org/10.15407/dopovidi2016.10.067Keywords:
activationless discharge, actual activation energy, barrierless discharge, classical discharge, latent heat of the electrode process, palladium(II) iminodiacetate complexes, true activation energyAbstract
The kinetic (exchange currents, apparent electron transfer coefficients) and energy (activation energy of diffusion and electron-transfer reaction) parameters of barrierless, ordinary (classic), and activationless discharge bis-iminodiacetate complexes of palladium(II) are determined. The actual and true activation energies and the latent heat of the electrode process are calculated.
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Kravtsov V.I. Rus. J. Elektrochem., 2004, 40, No 12: 1494-1502 (in Russian).
Kyblanovsky V.S., Nikitenko V.N. Electrochim. Acta, 2011, 56: 2110-2115. https://doi.org/10.1016/j.electacta.2010.11.028
Kyblanovsky V.S., Nikitenko V.N., Rudenko K.P. Ukr. Khim. Zhurn., 2012, 78, No 5: 47-51 (in Russian).
Kyblanovsky V.S., Nikitenko V.N. J. Electroanal. Chem., 2013, 699: 14-20. https://doi.org/10.1016/j.jelechem.2013.03.021
Damaskin B.B., Petrii O.A., Tsyrlina G.A. Elektrochemistry, Moscow: Khimiya, 2006 (in Russian).
Kublanovsky V.S., Nikitenko V.N., Rudenko K.P. Amer. J. Anal. Chem., 2013, 4: 642-646. https://doi.org/10.4236/ajac.2013.411076
Kublanovsky V.S., Nikitenko V.N., Rudenko K.P. Ukr. Khim. Zhurn., 2009, 75, No 7: 56-61.
Bard A.J., Faulkner L.R. Electrochemical Methods. Fundamental and Applications, New York: Wiley, 2001.
Gorodyskii A.V. Voltammetry. Kinetic of Stationary Electrolysis, Kiev: Nauk. Dumka, 1988 (in Russian).
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