Outlooks for reducing the content of platinum metals in catalysts for the hydrogenation of organic compounds
Transcript of scientific report at the meeting of the Presidium of NAS of Ukraine, February 22, 2023
DOI:
https://doi.org/10.15407/visn2023.04.085Abstract
The report states that the L.V. Pisarzhevsky Institute of Physical Chemistry of the NAS of Ukraine conducts relevant and important fundamental research on the influence of the structure of substances on their catalytic properties. Significant results have been obtained in the creation of new functional materials, such as catalysts for the hydrogenation of organic compounds, which have a significantly reduced content of platinum metals or do not contain them at all. The institute has substantial achievements in the field of productive catalysis for the fine organic synthesis of medication components and active substances for agrochemistry.
References
Oil Market Report. IEA. October 2022. https://www.iea.org/reports/oil-market-report-october-2022
Pharmaceuticals Global Market Report 2022. https://www.researchandmarkets.com/r/bndiyg
Global Agrochemicals Market Report. https://www.marketsandmarkets.com/Market-Reports/global-agro-chemicals-market-report-132.html
Guideline for elemental impurities. Committee for Human Medicinal Products. European Medicines Agency. Amsterdam, 2019.
Yoshii T., Nakatsuka K., Kuwahara Y., Mori K., Yamashita H. Synthesis of carbon-supported Pd–Co bimetallic catalysts templated by Co nanoparticles using the galvanic replacement method for selective hydrogenation. Royal Soc. Chem. Advances. 2017. 7(36): 22294. https://doi.org/10.1039/C7RA03846A
Gong Y., Zhang P., Xu X., Li Y., Li H., Wang Y. A novel catalyst Pd@ompg-C3N4 for highly chemoselective hydrogenation of quinoline under mild conditions. J. Catal. 2013. 297: 272. https://doi.org/10.1016/j.jcat.2012.10.018
Westerhaus F.A., Jagadeesh R.V., Wienhöfer G., Pohl M.-M., Radnik J., Surkus A.-E., Rabeah J., Junge K., Junge H., Nielsen M., Brückner A., Beller M. Heterogenized cobalt oxide catalysts for nitroarene reduction by pyrolysis of molecularly defined complexes. Nature Chem. 2013. 5: 537. https://doi.org/10.1038/nchem.1645
Yamada Y.M.A., Baek H., Sato T., Nakao A., Uozumi Y. Metallically gradated silicon nanowire and palladium nanoparticle composites as robust hydrogenation catalysts. Commun. Chemistry. 2020. 3: 81. https://doi.org/10.1038/s42004-020-0332-z
Ivanytsya M.O., Ryabukhin S.V., Volochnyuk D.M., Kolotilov S.V. Modern Approaches to the Creation of Immobilized Metal-Complex Catalysts for Hydrogenation, Alkene Metathesis, and Cross-Coupling Processes: A Review. Theor. Exp. Chem. 2020. 56(5): 283. https://doi.org/10.1007/s11237-020-09660-4
Asaula V.M., Lytvynenko A.S., Mishura A.M., Kurmach M.M., Buryanov V.V., Gavrilenko K.S., Ryabukhin S.V., Volochnyuk D.M., Kolotilov S.V. In-situ formation of NixB/MIL-101(Cr) and Pd/MIL-101(Cr) composites for catalytic hydrogenation of quinoline. Inorg. Chem. Comm. 2020. 121: 108203. https://doi.org/10.1016/j.inoche.2020.108203
Asaula V.M., Buryanov V.V., Solod B.Y., Tryus D.M., Pariiska O.O., Kotenko I.E., Volovenko Y.M., Volochnyuk D.M., Ryabukhin S.V., Kolotilov S.V. Catalytic Hydrogenation of Substituted Quinolines on Co-Graphene Composites. Eur. J. Org. Chem. 2021. 47: 6623. https://doi.org/10.1002/ejoc.202101311
Asaula V.M., Shvets O.V., Pariiska O.O., Bur’yanov V.V., Ryabukhin S.V., Volochnyuk D.M., Kolotilov S.V. Composites Based on Nanodispersed Nickel, Graphene-Like Carbon, and Aerosil for Catalytic Hydrogenation of Furfural and Quinoline. Theor. Exp. Chem. 2020. 56(4): 261. https://doi.org/10.1007/s11237-020-09657-z
Subotin V.V., Ivanytsya M.O., Terebilenko A.V., Yaremov P.S., Pariiska O.O., Akimov Y.M., Kotenko I.E., Sabov T.M., Kurmach M.M., Ryabukhin S.V., Volochnyuk D.M., Kolotilov S.V. Air-Stable Efficient Nickel Catalyst for Hydrogenation of Organic Compounds. Catalysts. 2023. 13(4): 706. https://doi.org/10.3390/catal13040706
Subotin V.V., Asaula V.M., Lishchenko Y.L., Ivanytsya M.O., Pariiska O.O., Ryabukhin S.V., Volochnyuk D.M., Kolotilov S.V. Catalytic reductive amination of aromatic aldehydes on Co-containing composites. Chemistry. 2023. 5(1): 281. https://doi.org/10.3390/chemistry5010022