Metal-organic framework compounds: what potential did the Nobel Committee see in them?
Nobel Prize in Chemistry 2025
DOI:
https://doi.org/10.15407/visn2025.12.031Keywords:
Nobel Prize in Chemistry 2025, Susumu Kitagawa, Richard Robson, Omar M. Yaghi, metal-organic frameworks.Abstract
This year, the Nobel Prize in Chemistry was awarded to three scientists — Japanese professor Susumu Kitagawa from the Institute for Integrated Cell-Material Sciences (iCeMS) at Kyoto University, British researcher Richard Robson from the University of Melbourne, and American chemist Omar M. Yaghi from the University of California, Berkeley — "for the development of metal-organic frameworks”. As noted in the Nobel Committee’s press release, the researchers have used the metal-organic frameworks they created to solve many pressing problems for humanity: harvest water from desert air, extract pollutants from water, capture carbon dioxide and store hydrogen, etc.
Cite this article:
Kolotilov S.V. Metal-organic framework compounds: what potential did the Nobel Committee see in them? (Nobel Prize in Chemistry 2025). Visn. Nac. Akad. Nauk Ukr. 2025. (12): 31—44. https://doi.org/10.15407/visn2025.12.031
References
Hoskins B.F., Robson R. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. J. Am. Chem. Soc. 1989. 111: 5962. https://doi.org/10.1021/ja00197a079
Li H., Eddaoudi M., O'Keeffe M., Yaghi O.M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature. 1999. 402: 276. https://doi.org/10.1038/46248
Farha O.K., Eryazici I., Jeong N.C., Hauser B.G., Wilmer C.E., Sarjeant A.A., Snurr R.Q., Nguyen S.T., Yazaydin A.Ö., Hupp J.T. Metal-organic framework materials with ultrahigh surface areas: is the sky the limit? J. Am. Chem. Soc. 2012. 134(36): 15016. https://doi.org/10.1021/ja3055639
Sengupta D., Melix P., Bose S., Duncan J., Wang X., Mian M.R., Kirlikovali K.O., Joodaki F., Islamoglu T., Yildirim T., Snurr R.Q., Farha O.K. Air-stable Cu (I) metal-organic framework for hydrogen storage. J. Am. Chem. Soc. 2023. 145: 20492. https://doi.org/10.1021/jacs.3c06393
Lin J.-B., Nguyen T.T.T., Vaidhyanathan R., Burner J., Taylor J.M., Durekova H., Akhtar F., Mah R.K., Ghaffari-Nik O., Marx S., Fylstra N., Iremonger S.S., Dawson K.W., Sarkar P., Hovington P., Rajendran A., Woo T.K., Shimizu G.K.H. A scalable metal-organic framework as a durable physisorbent for carbon dioxide capture. Science. 2021. 374: 1464. https://doi.org/10.1126/science.abi7281
Luo J., Luo X., Xie M., Li H.-Z., Duan H., Zhou H.-G., Wei R.-J., Ning G.-H., Li D. Selective and rapid extraction of trace amount of gold from complex liquids with silver (I)-organic frameworks. Nature Commun. 2022. 13: 7771. https://doi.org/10.1038/s41467-022-35467-z
Abtab S.M.T., Alezi D., Bhatt P.M., Shkurenko A., Belmabkhout Y., Aggarwal H., Weseliński Ł.J., Alsadun N., Samin U., Hedhili M.N., Eddaoudi M. Reticular chemistry in action: a hydrolytically stable MOF capturing twice its weight in adsorbed water. Chem. 2018. 4(1): 94. https://doi.org/10.1016/j.chempr.2017.11.005
Bavykina A., Kolobov N., Khan I.S., Bau J.A., Ramirez A., Gascon J. Metal-organic frameworks in heterogeneous catalysis: recent progress, new trends, and future perspectives. Chem. Rev. 2020. 120(16): 8468. https://doi.org/10.1021/acs.chemrev.9b00685
Carson F., Agrawal S., Gustafsson M., Bartoszewicz A., Moraga F., Zou X., Martín-Matute B. Ruthenium complexation in an aluminium metal-organic framework and its application in alcohol oxidation catalysis. Chem. Eur. J. 2012. 18: 15337. https://doi.org/10.1002/chem.201200885
Sun N., Shah S.S.A., Lin Z., Zheng Y.-Z., Jiao L., Jiang H.-L. MOF-based electrocatalysts: an overview from the perspective of structural design. Chem. Rev. 2025. 125(5): 2703. https://doi.org/10.1021/acs.chemrev.4c00664
Kuang X., Ma Y., Su H., Zhang J., Dong Y.-B., Tang B. High-performance liquid chromatographic enantioseparation of racemic drugs based on homochiral metal-organic framework. Anal. Chem. 2014. 86(2): 1277. https://doi.org/10.1021/ac403674p
Pramanik S., Hu Z., Zhang X., Zheng C., Kelly S., Li J. A systematic study of fluorescence-based detection of nitroexplosives and other aromatics in the vapor phase by microporous metal-organic frameworks. Chem. Eur. J. 2013. 19: 15964. https://doi.org/10.1002/chem.201301194
Yuan B., Pan Y., Li Y., Yin B., Jiang H. A highly active heterogeneous palladium catalyst for the Suzuki—Miyaura and Ullmann coupling reactions of aryl chlorides in aqueous media. Angew. Chem. Int. Ed. 2010. 49: 4054. https://doi.org/10.1002/anie.201000576
Phang W.J., Jo H., Lee W.R., Song J.H., Yoo K., Kim B., Hong C.S. Superprotonic conductivity of a UiO-66 framework functionalized with sulfonic acid groups by facile postsynthetic oxidation. Angew. Chem. Int. Ed. 2015. 54: 5142. https://doi.org/10.1002/anie.201411703
Kondo M., Yoshitomi T., Matsuzaka H., Kitagawa S., Seki K. Three-dimensional framework with channeling cavities for small molecules: {[M2(4,4′-bpy)3(NO3)4]·xH2O}n (M = Co, Ni, Zn). Angew. Chem. Int. Ed. 1997. 36(16): 1725. https://doi.org/10.1002/anie.199717251
Serre C., Millange F., Thouvenot C., Noguès M., Marsolier G., Louër D., Férey G. Very large breathing effect in the first nanoporous chromium (III)-based solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2Oy. J. Am. Chem. Soc. 2002. 124(45): 13519. https://doi.org/10.1021/ja0276974
Polunin R.A., Kolotilov S.V., Kiskin M.A., Cador O., Golhen S., Shvets O.V., Ouahab L., Dobrokhotova Z.V., Ovcharenko V.I., Eremenko I.L., Novotortsev V.M., Pavlishchuk V.V. Structural flexibility and sorption properties of 2D porous coordination polymers constructed from trinuclear heterometallic pivalates and 4,4'-bipyridine. Eur. J. Inorg. Chem. 2011. 2011: 4985. https://doi.org/10.1002/ejic.201100791
Pavlishchuk A.V., Kolotilov S.V., Zeller M., Shvets O.V., Fritsky I.O., Lofland S.E., Addison A.W., Hunter A.D. Magnetic and sorption properties of supramolecular systems based on pentanuclear copper (II) 12-metallacrown-4 complexes and isomeric phthalates: structural modeling of the different stages of alcohol sorption. Eur. J. Inorg. Chem. 2011. 2011: 4826. https://doi.org/10.1002/ejic.201100790
Guo J., Chu S., Yuan F., Otake K., Yao M.-S., Kitagawa S. Soft porous crystals: flexible MOFs as a new class of adaptive materials. Ind. Chem. Mater. 2025. 3: 651. https://doi.org/10.1039/D5IM00067J
Sotnik S.A., Polunin R.A., Kiskin M.A., Kirillov A.M., Dorofeeva V.N., Gavrilenko K.S., Eremenko I.L., Novotortsev V.M., Kolotilov S.V. Heterometallic coordination polymers assembled from trigonal trinuclear Fe2Ni-pivalate blocks and polypyridine spacers: topological diversity, sorption, and catalytic properties. Inorg. Chem. 2015. 54: 5169. https://doi.org/10.1021/ic503061z
Lytvynenko A.S., Kolotilov S.V., Kiskin M.A., Cador O., Golhen S., Aleksandrov G.G., Mishura A.M., Titov V.E., Ouahab L., Eremenko I.L., Novotortsev V.M. Redox-active porous coordination polymers prepared by trinuclear heterometallic pivalate linking with the redox-active nickel (II) complex: synthesis, structure, magnetic and redox properties, and electrocatalytic activity in organic compound dehalogenation in heterogeneous medium. Inorg. Chem. 2014. 53: 4970. https://doi.org/10.1021/ic403167m
Gurtovyi R.I., Tsymbal L.V., Kuzmin R.M., Odynets I.V., Lampeka Ya.D. Effect of the redox properties of the zinc and nickel metal-organic frameworks on peculiarities of their interaction with iodine and the electronic conductivity of the composites formed. Theor. Exp. Chem. 2016. 52: 104. https://doi.org/10.1007/s11237-016-9457-7
Polunin R.A., Burkovskaya N.P., Satska J.A., Kolotilov S.V., Kiskin M.A., Aleksandrov G.G., Cador O., Ouahab L., Eremenko I.L., Pavlishchuk V.V. Solvent-induced change of electronic spectra and magnetic susceptibility of CoII coordination polymer with 2,4,6-tris(4-pyridyl)-1,3,5-triazine. Inorg. Chem. 2015. 54: 5232. https://doi.org/10.1021/acs.inorgchem.5b00179