Features of the initial stage of oxidation of N-hydroxyphthalimide by potassium permanganate

Authors

  • L. I. Opeyda Department of Physical Chemistry of Fossil Fuels of the L. M. Litvinenko Institute of Physico- Organic and Coal Chemistry of the NAS of Ukraine, Lviv
  • A. F. Popov L. M. Litvinenko Institute of Physico-Organic and Coal Chemistry of the NAS of Ukraine, Kiev

DOI:

https://doi.org/10.15407/dopovidi2016.04.086

Keywords:

hydratation, N-hydroxyphthalimide, phthalimide-N-oxyl radical, potassium permanganate, protonation, quantum-chemical method

Abstract

The kinetics of oxidation of N-hydroxyphthalimide by potassium permanganate in acetone and its mixtures with water is studied. The accelerating effect of water on the kinetics of the initial stage of the process has been shown. Using the method of quantum chemistry, the reactivity of particles participating in the reaction of H-atom abstraction from the NO−H bond and the influence of protonation and hydratation was evaluated that gives possibility to explain the basic kinetic patterns obtained experimentally.

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Published

19.10.2024

How to Cite

Opeyda, L. I., & Popov, A. F. (2024). Features of the initial stage of oxidation of N-hydroxyphthalimide by potassium permanganate . Reports of the National Academy of Sciences of Ukraine, (4), 86–91. https://doi.org/10.15407/dopovidi2016.04.086

Issue

No. 4 (2016): Reports of the National Academy of Sciences of Ukraine

Section

Chemistry

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