The coaction of metallic Co and Mn microparticles and N-hydroxyphthalimide in the liquid-phase oxidation of cumene
DOI:
https://doi.org/10.15407/dopovidi2017.08.080Keywords:
Co and Mn microparticles, molecular oxygen, N-hydroxyphthalimide, radical chain oxidation catalysisAbstract
The action of metallic microparticles Co and Mn (CoMP and MnMP) in the process of radical-chain oxidation of cumene initiated with azobisisobutyronitrile by molecular oxygen in a solution of acetonitrile is investigated. A growth of the reaction rate in the case of adding the catalyst mixture of N-hydroxyphthalimide and MeMP is found. It is shown that the catalytic effect of CoMP and MnMP may be explained by their participation in the initiation stage of oxidation.
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