The influence of various factors on the photodegradation of methyl orange in the presence of titanium dioxide and β-cyclodextrin derivatives

Authors

  • O.A. Opanasenko
  • S.V. Riabov
  • S.I. Sinelnikov
  • Yu.Yu. Kercha

DOI:

https://doi.org/10.15407/dopovidi2014.01.130

Keywords:

methyl orange, photodegradation, titanium dioxide

Abstract

The photodegradation process of methyl orange is studied in the presence of TiO2 and β-cyclodextrin, and its derivatives. It is found that β-CD's maleates and acrylates significantly increase the intensity of this process (about 1.5–2 times). The factors such as pH of the medium, the concentration and surface-active properties of β-CD derivatives, which influence the process of passing dye photodegradation were investigated. The results obtained indicate that the optimum pH of the medium for effective methyl orange destruction ranges from 3 to 5. A direct relationship between the individual parameters of surface-active characteristics of β-CD derivatives is established.

Downloads

References

Gogate P. R., Pandit A. B. J. Adv. Environ. Res., 2004, 8, 501–551. https://doi.org/10.1016/S1093-0191(03)00032-7

US EPA, National Emission Standards for Hazardous Air Pollutants, 40 CFR, part 63. In: Federal Register, Rules and Regulations, 2008, 73, No. 7: 1–39.

Golikov A. P., Deineka O. G., Pozdniakova L. O., Chernomaz P. O. Regional economics and Nature: Studies. manuals. Kyiv: Center of educational literature, 2009 (in Ukrainian).

Fedotova M. P. Superfine bicomponent photocatalysts based on titanium dioxide. (Extended abstract of candidate thesis). Tomsk State University. Tomsk, Russia, 2009 (in Russian).

Wang G., Qi P., Xue X. et al. J. Sci. Direct., 2007, 67: 762–769.

Wang G., Wu F., Zhang X. et al. J. Hazardous Mater., 2006, 133: 85–91. https://doi.org/10.1016/j.jhazmat.2005.09.058

Gaya U. I., Abdullah A. H. J. Photochem. and Photobiol. C: Photochem. Rev., 2008, 9: 1–12. https://doi.org/10.1016/j.jphotochemrev.2007.12.003

Babich I. V., Ryabov S. V., Sinelnikov S. I. et al. Ukr. khim. zhurn., 2012, 78, No. 9./10.: 64–68 (in Ukrainian).

Ambramzon A. A., Shchukin E. D. (Eds.). Surface phenomena and surface-active substances. Leningrad: Khimiia, 1984 (in Russian).

Fainerman A. E., Lipatov Yu. S., Kulik V. M. et al. Kolloid. zhurn., 1970, 32: 620–623 (in Russian).

Published

24.03.2025

How to Cite

Opanasenko, O., Riabov, S., Sinelnikov, S., & Kercha, Y. (2025). The influence of various factors on the photodegradation of methyl orange in the presence of titanium dioxide and β-cyclodextrin derivatives . Reports of the National Academy of Sciences of Ukraine, (1), 130–135. https://doi.org/10.15407/dopovidi2014.01.130