X-ray diffraction analysis of the polymorphic transition of lead oxide in a polymer matrix formed in constant physical fields

Authors

  • V. O. Vilensky
  • Y.V. Bardadym
  • Y.P. Gomza
  • Y.Y. Kercha

DOI:

https://doi.org/10.15407/dopovidi2014.10.069

Keywords:

lead oxide, physical fields, X-ray diffraction analysis

Abstract

The influence of physico-chemical factors at forming the three-dimensional network of a thermosetting plastic under the simultaneous action of constant physical fields upon the crystalline β-form of PbO is first studied. X-ray structural analysis of composites on the base of polyepoxy-lead monoxide and polyaniline showed the formation of a new crystal ϕ-phase.Constant physical fields and polyaniline intensify the processes of condensation and crystallization of the formed phase. It is established that the crystallization of the ϕ-phase occurs under the simultaneous action of physical fields and polyaniline and each factor independently.

Downloads

References

Soderquist R., Diskens B. J. Phys. Chem. Solids., 1967, 28: 823–827. https://doi.org/10.1016/0022-3697(67)90011-X

Vilenskyi V. O., Demchenko V. L. Polimer. zhyrn., 2008, 30, No 2: 133–140 (in Ukrainian).

Demchenko V. L., Vilenskyi V. O. Polimer. zhyrn., 2009, 31, No 2: 97–110 (in Ukrainian).

Bardadym Yu. V., Vilrenskyi V. O., Gomza Yu. P., Kercha Yu. Yu. Dopov. Nac. akad. nauk Ukr., 2014, No 1: 63–71 (in Ukrainian).

Pat. 61-266435 JP, IPC C08G73/00, H01L29/28. Method of Preparation of Thin Films of Conducting Organic Polymers, Tamura S., Publ. 06.11.1986.

Light T. B., Eldridge J. M., Matthews J. W. J. Appl. Physics, 1975, 46, No 4: 1489–1492. https://doi.org/10.1063/1.321799

Kay M. I. Acta Cryst., 1961, 14: 80. https://doi.org/10.1107/S0365110X61000309

Wang H. Modern Appl. Science, 2010, 4, No 4: 143.

Mirkin L. I. Guide to x- ray structural analysis of polycrystalline, Moscow: Gos. izd-vo fiz.-mat. nauk, 1961 (in Russian).

Runt J., Fitzgerald J. J. Dielectric spectroscopy of polymeric materials. Fundamentals and applications, Washington: Amer. Chem. Society, 1997.

Dickinson R. G., Friauf J. B. J. Amer. Chem. Soc., 1924, 46, No 11: 2457–2463. https://doi.org/10.1021/ja01676a015

Trinquier G., Hoffman R. J. Phys. Chem., 1984, 88: 6696–6711. https://doi.org/10.1021/j150670a038

Published

06.03.2025

How to Cite

Vilensky, V. O., Bardadym, Y., Gomza, Y., & Kercha, Y. (2025). X-ray diffraction analysis of the polymorphic transition of lead oxide in a polymer matrix formed in constant physical fields . Reports of the National Academy of Sciences of Ukraine, (10), 69–75. https://doi.org/10.15407/dopovidi2014.10.069