Specificities of the formation of epoxy-acrylate interpenetrating polymer networks under the Sun radiation

Authors

  • T. F. Samoilenko
  • N.V. Iarova
  • G.Y. Menzheres
  • O. O. Brovko

DOI:

https://doi.org/10.15407/dopovidi2014.07.122

Keywords:

interpenetrating polymer networks, Sun radiation

Abstract

Kinetic specificities of the simultaneous epoxy-acrylate interpenetrating polymer networks synthesis under the solar radiation are investigated. The comparative analysis of the degree of functional groups conversion for the polymerization under artificial and natural conditions is made. It is found that the epoxy groups conversion is higher under the solar irradiation than under the irradiation of a UV lamp, and the double bonds conversion is actually the same for both systems.

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References

Decker C., Bendaikha T. J. Appl. Polym. Sci., 1998, 70: 2269–2282. https://doi.org/10.1002/(SICI)1097-4628(19981212)70:11<2269::AID-APP21>3.0.CO;2-D

Lalevee J., Fouassier J. P. Polym. Chem., 2011, 2: 1107. https://doi.org/10.1039/c1py00073j

Samoilenko T. F., Yarova N. V., Menzheres G. Ya. et al. IR-spectroscopic study of polonizirovannaya polymerization of epoxy resins UE-650 T, triethyleneglycoldinitrate and compositions on their basis. Proceedings of the XIII Ukrainian Conference on Macromolecules «BMC-2013», Kyiv, Institute of macromolecular chemistry NAS of Ukr., 2013: 290–292 (in Ukrainian).

Menzheres G. Ya., Dyadyusha A. G., Vatulaev V. N. et al. Zhurn. prikl. khimii, 1989, 10: 2348–2352 (in Russian).

Bellami L. Infrared spectra of complex molecules. Moscow: Izd-vo inostr. lit., 1963 (in Russian).

De Brito M., Allonas X., Croutxe-Barghorna C. et al. Progr. Organ. Coatings., 2012, 73: 186–193. https://doi.org/10.1016/j.porgcoat.2011.10.014

Grishchenko V. K., Maslyuk A. F., Gudzera S. S. Liquid photopolymerizable compositions. Kyiv: Nauk. dumka, 1985 (in Russian).

Polymer products from Aldrich. Applications: free radical initiators. 1999.

Published

28.02.2025

How to Cite

Samoilenko, T. F., Iarova, N., Menzheres, G., & Brovko, O. O. (2025). Specificities of the formation of epoxy-acrylate interpenetrating polymer networks under the Sun radiation . Reports of the National Academy of Sciences of Ukraine, (7), 122–126. https://doi.org/10.15407/dopovidi2014.07.122