Synthesis and crystal structure of layer perovskites Sr3LnBIIISnO8 (BIII — Sc, In)

Authors

  • Y. A. Titov
  • N. M. Belyavina
  • V. Ya. Markiv
  • M. S. Slobodyanik
  • V. V. Polybinskii

DOI:

https://doi.org/10.15407/dopovidi2014.04.133

Keywords:

layer perovskites, structure, synthesis

Abstract

The boundaries of the morphotropic transition in the Sr3LnBIIISnO8 (BIII — Sc, In) monoslab perovskites with layer perovskite-like structures (LPS) have been defined. The Sr3LnInSnO8 (Ln — La, Pr, Nd) and Sr3LaScSnO8 compounds have been synthesized, and their LPS is determined by X-ray powder diffraction. It is found that the LPS of Sr3LnInSnO8 (Ln — La, Pr, Nd) and Sr3LaScSnO8 belong to the SrLaInO4-type structure (sp. gr. Pbca). The final RB values are equal to 0.055–0.063. The peculiarities of LPS for Sr3LnInSnO8 (Ln — La, Pr, Nd) and Sr3LaScSnO8 have been analyzed, and the correlations between their composition and constitution of LPS are found.

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References

Aleksandrov K. S., Beznosikov B. V. Perovskites. Present and Future. Novosibirsk: Nauka SO RAN, 2004 (in Russian).

Schaak R. E., Mallouk T. E. Chem. Mater., 2002, 14, No. 4: 1455–1471. https://doi.org/10.1021/cm010689m

Kim I.-S., Nakamura T., Itoh M. J. Ceram. Soc. Jap. Int., 1993, 101, No. 7: 779–782.

Kim I.-S., Kawaji H., Itoh M., Nakamura T. Mater. Res. Bull., 1992, 27, No. 10: 1193– 1203. https://doi.org/10.1016/0025-5408(92)90227-Q

Zhaofei L., Guobao L., Junliang S. et al. Solid State Sci., 2006, 8, No. 9: 1035– 1040. https://doi.org/10.1016/j.solidstatesciences.2005.12.015

Titov Yu. O., Slobodyanyk M. S., Kraevska Ya. A. Ukr. khim. zhurn., 2008, 74, No. 7: 17–22 (in Ukrainian).

Titov Yu. O., Slobodyanyk M. S., Kraevska Ya. A. Ukr. khim. zhurn., 2011, 77, No. 6: 73–76 (in Ukrainian).

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Published

17.02.2025

How to Cite

Titov, Y. A., Belyavina, N. M., Markiv, V. Y., Slobodyanik, M. S., & Polybinskii, V. V. (2025). Synthesis and crystal structure of layer perovskites Sr3LnBIIISnO8 (BIII — Sc, In) . Reports of the National Academy of Sciences of Ukraine, (4), 133–138. https://doi.org/10.15407/dopovidi2014.04.133

Issue

No. 4 (2014): Reports of the National Academy of Sciences of Ukraine

Section

Chemistry

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