The velocity and absorption of sound near the critical point of stratification in the solution nitrobenzene–n-hexane
DOI:
https://doi.org/10.15407/dopovidi2016.08.053Keywords:
absorption of ultrasound, binary mixture, critical point of stratification, lifetime of fluctuations of the concentration, velocityAbstract
The acoustic research of a binary solution nitrobenzene–n-hexane with various concentrations in a wide range of frequencies near its upper critical point of stratification is executed. It is shown that, by the dynamic scaling theory, the velocity of sound should be analyzed separately in three dynamic areas, where the role of fluctuations is absent, significant, or is on the verge of definition. Analysis of the temperature dependence of the velocity of ultrasound allowed us to estimate the lifetime of fluctuations of the concentration in the solution nitrobenzene–n-hexane at its approach to the critical point from the homogeneous state up to 0.1 K.
Downloads
References
Bhattacharjee K., Mirzaev S. Z., Kaatze U. Int. J Thermophys, 2012: 469–483. DOI: https://doi.org/10.1007/s10765-012-1167-3
Abdelraziq Issam R., Yun S. S., Stumpf F. B. J. Acoustic. Soc. Am., 1990, 89, No 4: 1831–1836.
Mirzaev S. Z., Kaatze U. Chem. Phys., 2012, 393: 129. DOI: https://doi.org/10.1016/j.chemphys.2011.11.035
Iwanowski I., Mirzaev S. Z., Orzechowski K., Kaatze U. J. Molecular Liquids, 2009, 145: 103–108. DOI: https://doi.org/10.1016/j.molliq.2009.01.001
Kozlovskii M. P. Condens. Matter. Phys., 2005, 8: 473–506. DOI: https://doi.org/10.5488/CMP.8.3.473
Chalyy K. A., Bulavin L. A., Chalyi A. V. J. Phys. Studies, 2005, 9, No 1: 66–70.
Shytilov V. A. Basics of ultrasound physics, Leningrad, Izd. LU, 1980.
Fixman M. J. Chem. Phys., 1962, 36: 1961–1964. DOI: https://doi.org/10.1063/1.1732810
Patashinskii A. Z., Pokrovsky V. L. Fluctuation theory of phase transitions. Moscow, Nauka, 1982 (in Russian).
Anisimov M. A. Critical phenomena in liquid crystals, Moskva, Nauka, 1987 (in Russian).
Artemenko S., Lozovsky T., Mazur V. J. of Phys. Condensed Matter., 2008, 20: 244119,8.
Bulavin L. A, Chekhun, V. F. Vasilkevich O. A. et al. J. Phys. Studies, 2004, 8, No 4: 334–337.
Sperkach V. S., Alekhin A. D., Bilous O. I. Ukr. J. Phys., 2004, 49: 655–658.
Hill R. M. Phys. Stat. Sol., 1981, 103, No 1: 231–239. DOI: https://doi.org/10.1002/pssb.2221030135
Bhattacharjee J. K., Ferrell R. A. Phys. Rev. A, 1981, 24: 1643–1647. DOI: https://doi.org/10.1103/PhysRevA.24.1643
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Reports of the National Academy of Sciences of Ukraine
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.