Synthesis of 4,4′-bis(nonafluorobiphenyl-4-oxyphenyl)- 1,4-oxytetrafluorobenzene and ladder spirobisindane-containing polyether on its base

Authors

  • I. М. Tkachenko Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • Ya. L. Kobzar Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • V. V. Kravchenko L. M. Litvinenko Institute of Physical-Organic and Coal Chemistry of the NAS of Ukraine, Kiev
  • О. V. Shekera Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • V. V. Shevchenko Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev

DOI:

https://doi.org/10.15407/dopovidi2016.07.100

Keywords:

fluorinated poly(arylene ether)s, ladder polymers, perfluorinated fragments, PIM polymers, spirobisindane

Abstract

A method of synthesis of 4,4′-bis(nonafluorobiphenyl-4-oxyphenyl)-containing monomer with tetrafluorobenzene central unit based on decafluorobiphenyl and 4-[2,3,5,6-tetrafluoro-4-(4-hydroxyphenoxy) phenoxy]phenol is developed. Ladder type aromatic polyether is synthesized by the interaction of the obtained monomer with spiro-bis-catechol 5,5′,6,6′-tetrahydroxy-3,3,3′,3′-tetramethyl-1,1′-spirobisindane. The presence of both rigid dibenzodioxin and spirobisindane fragments (site of contortion) in its structure leads to decreasing the packing density of macromolecular chains that is promising for the regulation of transport properties of polymeric systems.

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References

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Published

15.11.2024

How to Cite

Tkachenko I. М., Kobzar, Y. L., Kravchenko, V. V., Shekera О. V., & Shevchenko, V. V. (2024). Synthesis of 4,4′-bis(nonafluorobiphenyl-4-oxyphenyl)- 1,4-oxytetrafluorobenzene and ladder spirobisindane-containing polyether on its base . Reports of the National Academy of Sciences of Ukraine, (7), 100–106. https://doi.org/10.15407/dopovidi2016.07.100

Issue

No. 7 (2016): Reports of the National Academy of Sciences of Ukraine

Section

Chemistry

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