Development and Modification of Photopolymerized Adhesives for Technological Processes of Framed Print Production

Authors

  • V. Granchak L. V. Pisarzhevskii Institute of the Physical Chemistry NAS of Ukraine, Kyiv
  • V. Sysyuk Institute of Macromolecular Chemistry NAS of Ukraine, Kyiv
  • P. Davyskyba Institute of Macromolecular Chemistry NAS of Ukraine, Kyiv
  • A. Bubnova Institute of Macromolecular Chemistry NAS of Ukraine, Kyiv
  • V. Majik About Ukrainian Academy of Printing, Lviv
  • L. Yasynska About Ukrainian Academy of Printing, Lviv

DOI:

https://doi.org/10.15407/scin8.03.023

Keywords:

photo adhesive, composite material, photopolymerization, modifier, photoinitiator, actinity, kinetics, synthesis, finishing, embossing.

Abstract

 To improve physical and chemical, mechanical and adhesive properties of polymerizable compositions the directions of their modification were defined. A photosensitive composite material based on oligouretanacrylate aliphatic nature, oligoetheracrylate, photoinitiator system was developed. To increase the rate of coating curing the synthesis of oligomeric modifiers was conducted. The relationship between the kinetic parameters of photopolymerization and properties of the polymer coatings was determined, the directions of regulation of their functionality when interacting with different oligomeric modifiers to improve lightsensitivity and adhesion strength were defined. A pilot batch of photopolymer adhesive was produced with the next material testing at the manufacture.

References

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Published

2024-06-05

Issue

Section

Research and Engineering Innovative Projects of the National Academy of Sciences of Ukraine