Influence of the structurization of water on the pressure of its saturated vapor and on the surface tension
DOI:
https://doi.org/10.15407/dopovidi2018.03.080Keywords:
mathematical functions, molecular liquids, structure-dependent properties, structurizing, waterAbstract
On the basis of the assumption that homogeneously structured liquids have a permanent energy of activation, two functions are constructed for the pressure of saturated vapors (3√P=f(T)) and for the surface tension of water (√ σ =f(T)) that can keep straightforwardness under the thermobaric conditions of existence of the corresponding structures. Calculations have showed that the first function well describes 4-phase changes of a water structure at the heating, and it is suitable for the analysis of the structurization in other liquids. The second function confirms the homogeneity of structures of the interface in waters of I and II types and the absence of a surface structurization in waters of III and IV types.
Downloads
References
Daniels, R. & Alberty, P. (1967). Physical Chemistry. Moscow: Vysshaya Shkola (in Russian).
Horn, R. (1972). Marine chemistry (water structure and chemistry of the hydrosphere). Moscow: Mir (in Russian).
Antonchenko, V. Ya., Davydov, A. S. & Il'in, V. V. (1991). Foundations of physics of water. Kiev: Naukova Dumka (in Russian).
Azarkish, H., Behzadmehr, A., Fanaei Sheikholeslami, T., Sarvari, S. M. H. & Fréchette, L. G. (2015). Water evaporation phenomena on micro and nanostructured surfaces. Int. J. Therm. Sci., 90, pp. 112-121. doi: https://doi.org/10.1016/j.ijthermalsci.2014.12.005
Bochkarev, A. A. & Polyakova, V. I. (2014). Emission of dimers from free-form of the heated water. Prikl. mehanika i tehn. fizika, 55, No. 5, pp. 115-125 (in Russian).
Khodorkovsky, M. A., Artamonova, T. O., Murashov, S. V., Michael, D., Rakcheeva, L. P, Belyaeva, A. A, Timofeev, N. A, Melnikov, A. S. & Shakhmin, A. L. (2007). Investigation of the composition of a mixture of water vapor with argon by the mass spectrometry method of a supersonic molecular beam. Zhurn. tehn. fiziki, 77, No. 10, pp. 16-23 (in Russian).
Kushnir, S. (2012). Structure and properties of clear water under different thermobaric conditions (physicalchemical analysis). Mineralog. Rev., No. 62, Iss. 2, pp. 236-245 (in Ukrainian).
Kushnir, S. V. (1995). Influence of salt waters is on katagenetichni transformation of the dissipated organic matter. Dopov. Nac. akad. nauk Ukr., No. 5, pp. 93-96 (in Ukrainian).
Kushnir, S. V. (2015). Reasons for the bubbling chemical effect and differentiation of ions in the formation of marine aerosols (physico-chemical analysis). Dopov. Nac. akad. nauk Ukr., No. 7, pp. 91-97 (in Ukrainian). doi: https://doi.org/10.15407/dopovidi2015.07.091
Rivkin, C. A. & Aleksandrov, A. A. (1980). Tepmophysical properties of water and aquatic steam. Moscow: Energiya (in Russian).
Smits, M., Ghosh, A., Sterrer, M., Muller, M. & Bonn, M. (2007). Ultrafast vibrational energy transfer between surface and bulk water at the air-water interface. Phys. Rev. Lett., 98, 098302. doi: https://doi.org/10.1103/PhysRevLett.98.098302
Zubarev, V. N., Prusakov, P. G. & Sergeeva, L. G. (1973). Tepmophysical properties of methyl alcohol. Moscow: Izd-vo standartov (in Russian).
Treger, Yu. A., Pipenov, I. F. & Gol'fand, E. A. (1973). Handbook on physico-chemical properties of clororganic compaunds of C1-C8. Leningrad: Khimiya (in Russian).
Nikol'skiy, B. P. (Eds.). (1962). Reference book of chemistry. Vol. 1. Leningrad, Moskow: Goshimizdat (in Russian).
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Reports of the National Academy of Sciences of Ukraine
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
