Synthesis of polyhedral oligomeric silsesquioxane containing azobenzene chromophore with hydroxymethylene group in the organic part of the core

Authors

  • I. М. Tkachenko Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • Ya. L. Kobzar Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • A. V. Sidorenko Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • О. V. Shekera Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • V. V. Shevchenko Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev

DOI:

https://doi.org/10.15407/dopovidi2016.08.092

Keywords:

azochromophores, photoisomerization, polyhedral oligomeric silsesquioxane, SIG-groups

Abstract

A method of synthesis of the allyl-containing azobenzene chromophore with a hydroxymethylene group is developed by the reduction of an aldehyde group of 5-[2-phenyldiazene-1-yl]-2-(prop-2-en-1-yloxy)benzaldehyde. Organic-inorganic hybrid nanoparticles containing the azobenzene chromophore with a hydroxymethylene group in the organic part of the core are obtained by the interaction of the synthesized azochromophore with octakis(dimethylsilyloxy)silsesquioxane. The synthesized compounds were characterized by 1H, 13C NMR, IR and UV-vis spectroscopy techniques and can be considered for photoswitches, sensing devices, nonlinear optic and liquid crystal materials.

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Published

15.11.2024

How to Cite

Tkachenko I. М., Kobzar, Y. L., Sidorenko, A. V., Shekera О. V., & Shevchenko, V. V. (2024). Synthesis of polyhedral oligomeric silsesquioxane containing azobenzene chromophore with hydroxymethylene group in the organic part of the core . Reports of the National Academy of Sciences of Ukraine, (8), 92–100. https://doi.org/10.15407/dopovidi2016.08.092

Issue

No. 8 (2016): Reports of the National Academy of Sciences of Ukraine

Section

Chemistry

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