Synthesis of core-fluorinated bis(benzoxazine)-containing monomers with 1,4-tetrafluorobenzene or 4,4′-octafluorobiphenylene dioxyphenylene central units

Authors

  • Ya. L. Kobzar Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • I. M. Tkachenko Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • O. V. Shekera Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev
  • V. V. Shevchenko Institute of Macromolecular Chemistry of the NAS of Ukraine, Kiev

DOI:

https://doi.org/10.15407/dopovidi2016.06.079

Keywords:

core-fluorinated monomers, benzoxazines, polybenzoxazines

Abstract

New bis(benzoxazine)-containing compounds with 1,4-tetrafluorobenzene or 4,4′-octafluorobiphenylene dioxyphenylene central units are obtained by the reductive amination of azomethine-containing bisphenols with subsequent condensation of the obtained compounds with paraformaldehyde. The structure of synthesized monomers was characterized by IR, 1H, 13C, and 19F NMR spectroscopy techniques. The synthesized compounds are of interest as monomers for the synthesis of corefluorinated polybenzoxazines.

Downloads

Download data is not yet available.

References

Ishida H., Agag T., Eds. Handbook of benzoxazine resins, Amsterdam etc.: Elsevier, 2011.

Wang Y.-S., Hung H.-C., Lee C.-H., Hung H.-W. Int. J. Nanomanufacturing, 2013, 9, No 1: 1–9.

Wu J., Xi Y., McCandless G. T., Xie Y., Menon R., Patel Y., Yang D. J., Iacono S. T., Novak B. M.

Macromolecules, 2015, 48, No 17: 6087–6095.

Velez-Herrera P., Ishida H. J. Fluorine Chem., 2009, 130, No 6: 573–580.

Demir K. D., Kiskan B., Latthe S. S., Demirel A. L., Yagci Y. Polym. Chem., 2013, 4, No 6: 2106–2114.

Semerci E., Kiskan B., Yagci Y. Eur. Polym. J., 2015, 69: 636–641.

Bektas S., Kiskan B., Orakdogen N., Yagci Y. Polymer, 2015, 759: 44–50.

Velez-Herrera P., Doyama K., Abe H., Ishida H. Macromolecules, 2008, 41, No 24: 9704–9714.

Liu Y. L., Lin G. C., Wu C. S. J. Polym. Sci., Part A: Polym. Chem., 2007, 45, No 5: 949–954.

Shevchenko V., Tkachenko I., Shekera O. Polym. Sci. Ser. B, 2010, 52, No 7./8: 408–430.

Tkachenko I. M., Kobzar Ya. L., Shekera O. V., Shechenko V. V. Ukr. Chem. J., 2014, 80, No 1–2: 114–120 (in Russian).

Organikum, 2 Vol., Moscow: Mir, 2008 (in Russian).

Su Y.-C., Chang F.-C. Polymer, 2003, 44, No 26: 7989–7996.

Lin C. H., Chang S. L., Lee H. H., Chang H. C., Hwang K. Y., Tu A. P., Su W. C. J. Polym. Sci., Part A:

Polym. Chem., 2008, 46, No 15: 4970–4983.

Lin C. H., Chang S. L., Hsieh C. W., Lee H. H. Polymer, 2008, 49, No 5: 1220–1229.

Downloads

Published

03.11.2024

How to Cite

Kobzar, Y. L., Tkachenko, I. M., Shekera, O. V., & Shevchenko, V. V. (2024). Synthesis of core-fluorinated bis(benzoxazine)-containing monomers with 1,4-tetrafluorobenzene or 4,4′-octafluorobiphenylene dioxyphenylene central units. Reports of the National Academy of Sciences of Ukraine, (6), 79–86. https://doi.org/10.15407/dopovidi2016.06.079

Issue

No. 6 (2016): Reports of the National Academy of Sciences of Ukraine

Section

Chemistry

License

Copyright (c) 2024 Reports of the National Academy of Sciences of Ukraine

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.